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Important Questions for "organic chemistry":
[1]
Which electronic configurations have opposite energy levels in Orgel diagrams under the same ligand field?
Which symbiotic bacteria fixes nitrogen?
Which one is not a micronutrient?
[2]
Describe the splitting pattern and intensity of peaks for hydrogens in CICH2-C(CI)-CH3.
Compare the coupling constants (J) for allylic protons and ortho-aromatic protons.
Interpret the structure of a compound given PMR peaks at 7.22, 3.59, 2.77, and 0.97.
[3]
Define unimolecular nucleophilic substitution reactions.
Explain the association and dissociation mechanisms of base hydrolysis reactions.
Describe the application of Tanabe-Sugano diagrams in predicting spectral transitions.
[4]
What are products formed during bromination of butane in light conditions?
What are structural isomers of alkenes?
Describe dehydration processes yielding ethylene.
[5]
What is Bent's rule? Provide an example.
Define symmetry elements and symmetry operations with examples.
Discuss the chelate effect of ligands and its thermodynamic origin for stability of metal complexes.
[6]
Why is mesotartaric acid optically inactive despite having two chiral carbons?
Write notes on the Von Richter reaction and Gattermann-Koch reaction.
Discuss the mechanism of neighboring group participation.
[7]
Explain ionophores with suitable examples.
Discuss the structural features and mechanism carried out by xanthine oxidase.
Discuss the structure and biological function of NAD+ and NADP coenzymes.
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