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{"filename":"msc-2-sem-chemistry-physical-chemistry-2-7333-set-c-2024.pdf","subject":"Physical Chemistry-II","exam":"M.Sc. Second Semester Examination, 2024","sections":["Descriptive Questions"]}

Questions:

  1. Which of the following is a synthetic polymer?
  2. What is the primary benefit of using electrically conducting fire-resistant materials in electronic devices?
  3. Which electrically conducting fire-resistant material is commonly used in fire-resistant cables and insulation?
  4. Which of the following is a characteristic property of liquid crystal polymers?
  5. The degree of polymerization refers to?
  6. Which of the following compounds has the highest molecular mass?
  7. The rate of diffusion of macromolecules is inversely proportional to which parameter?
  8. What is the average dimension of branched polymers?
  9. What is the average dimension of linear chain polymer?
  10. Sedimentation viscometry provides information about which property?
  11. The Debye-Huckel theory is used to describe the behavior of activity coefficients in which type of solution?
  12. What does the Debye-Huckel theory predict about the activity coefficient of an ion with increasing concentration?
  13. What is the Debye-Huckel equation related to?
  14. The Debye-Huckel theory is most accurate for which type of ions?
  15. For which solutions is the Debye-Huckel theory applicable?
  16. What is the definition of ionic strength?
  17. The potential at the surface of a charged interface is referred to as what?
  18. The magnitude of overpotential can be reduced by which methods?
  19. The Tafel equation relates overpotential to which properties?
  20. Which law of thermodynamics states that energy cannot be created or destroyed?
  21. The second law of thermodynamics is known as what?
  22. Free energy is a measure of what?
  23. How is the change in free energy (G) of a reaction given?
  24. What does a negative G value indicate about a reaction?
  25. The chemical potential of a substance is a measure of which property?
  26. The chemical potential of a solvent in a solution is affected by which factors?
  27. What is partial molar volume (v)?
  28. What does partial molar free energy (G) represent for a component in a mixture?
  29. How is the partial molar volume of a component in an ideal solution given?
  30. Under what conditions is the partial molar property of a component in a mixture additive?
  31. Fugacity is commonly represented by which symbol?
  32. Which graphical plot is used to determine fugacity?
  33. In a fugacity diagram, what does the region below the curve represent?
  34. The activity coefficient is a measure of what?
  35. Which symbol is used to denote the activity coefficient?
  36. What does the Boltzmann distribution law describe about particles in a system?
  37. The Boltzmann distribution law is derived from which principles?
  38. Which type of motion does the rotational partition function apply to?
  39. On what assumption is the rotational partition function based?
  40. What is the vibrational partition function proportional to?
  41. For which type of motion is the vibrational partition function applicable?
  42. What assumption is the vibrational partition function based on?
  43. Fermi-Dirac statistics describe the behavior of which type of particles?
  44. To which particles is Fermi-Dirac statistics applicable?
  45. What characterizes non-equilibrium states?
  46. The first law of thermodynamics can be applied to which type of states?
  47. Entropy production is a measure of what?
  48. The entropy balance equation for fluid flow is based on which principle?
  49. Onsager's reciprocity relations hold for systems with which coefficients?
  50. The electrokinetic behavior of a system can be influenced by what factors?
  51. In non-equilibrium stationary systems, what affects the transformation of fluxes and forces?
  52. According to the Gibbs adsorption isotherm, what is surface coverage proportional to?
  53. The Gibbs adsorption isotherm is based on which assumption?
  54. The BET equation is used to estimate which property?
  55. The BET plot is a graph of which parameters?
  56. What assumption does the BET equation make about adsorption?
  57. What motion does the electrokinetic phenomenon refer to?
  58. The zeta potential measures which property?
  59. What factors affect the electrokinetic potential?
  60. Active sites on a catalyst surface are characterized by what?
  61. The rate of a catalyzed reaction is determined by which factors?
  62. What is the process of adsorption of reactant molecules on a catalyst surface typically like?
  63. What factors influence the catalytic activity of a surface?
  64. How is the adsorption of reactant molecules on a catalyst surface categorized?
  65. Surface-active agents work by which mechanisms?
  66. Which type of surfactant is commonly used in shampoos to produce foam?
  67. Surface-active agents can act as what?
  68. Which of the following is an example of nonionic surfactant?
  69. What is amphoteric surfactants characterized by?
  70. What does micellization refer to?
  71. What factors influence the critical micellar concentration (CMC) of surfactants?
  72. How is the critical micellar concentration (CMC) defined?
  73. Microemulsions are formed by the action of what?
  74. What is the process called by which monomers are linked together to form polymers?
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